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dc.contributor.authorKim, Pyoseop-
dc.contributor.authorKwon, YongSung-
dc.contributor.authorLee, Minseong-
dc.contributor.authorKim, DaeHun-
dc.contributor.authorPark, You-In-
dc.contributor.authorChoi, Nakwon-
dc.contributor.authorNam, Seung-Eun-
dc.contributor.authorChoi, Jungkyu-
dc.date.accessioned2024-01-19T09:30:11Z-
dc.date.available2024-01-19T09:30:11Z-
dc.date.created2023-11-15-
dc.date.issued2023-06-
dc.identifier.issn1383-5866-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/113614-
dc.description.abstractAmong the various zeolite membranes, hydrophilic Linde Type A (LTA) zeolite membranes (LTA membranes) are highly desirable for the dehydration of organic solvents. In particular, both high flux and separation factors for H2O can be achieved with such membranes. Therefore, in this study, we fabricated LTA membranes on thin-walled capillary tubes and compared the dehydration performance with those of LTA membranes prepared on conventional tubular supports. We found that neither LTA membrane contained noticeable defects using fluo-rescence confocal optical microscopy analysis. Accordingly, both membranes effectively dehydrated an azeo-tropic ternary mixture of H2O/isopropanol (IPA)/epichlorohydrin (ECH), an industrially important mixture. Specifically, the capillary-supported LTA membrane showed better dehydration performance than that on the conventional tubular support, mainly because of the relatively thinner support thickness (ca. 0.35 mm vs. 2 mm of the conventional tubular support). The corresponding H2O flux was ca. 8.02 +/- 0.94 kg center dot m- 2 center dot h-1 for the azeotropic ternary mixture (20 wt% H2O/30 wt% IPA/50 wt% ECH) at 70 degrees C (vs. 4.26 +/- 0.39 kg center dot m- 2 center dot h-1 through the LTA membrane on the conventional tube). Further, the H2O/IPA and H2O/ECH separation factors exceeded approximately 10,000. Finally, a comparison with the literature data revealed that the capillary-supported LTA membrane had higher H2O flux and selectivity for H2O/IPA mixtures than other LTA mem-branes prepared on conventional discs/sheets/tubes.-
dc.languageEnglish-
dc.publisherPergamon Press Ltd.-
dc.titleLTA zeolite membranes on thin-walled capillary tubes for the high-throughput dehydration of industrially important ternary water/isopropanol/epichlorohydrin mixtures-
dc.typeArticle-
dc.identifier.doi10.1016/j.seppur.2023.123733-
dc.description.journalClass1-
dc.identifier.bibliographicCitationSeparation and Purification Technology, v.315-
dc.citation.titleSeparation and Purification Technology-
dc.citation.volume315-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000978052900001-
dc.identifier.scopusid2-s2.0-85151543861-
dc.relation.journalWebOfScienceCategoryEngineering, Chemical-
dc.relation.journalResearchAreaEngineering-
dc.type.docTypeArticle-
dc.subject.keywordPlusNAA ZEOLITE-
dc.subject.keywordPlusHIGH-PERFORMANCE-
dc.subject.keywordPlusHOLLOW-FIBER-
dc.subject.keywordPlusNANOCOMPOSITE MEMBRANE-
dc.subject.keywordPlusHYDROTHERMAL SYNTHESIS-
dc.subject.keywordPlusMICROWAVE SYNTHESIS-
dc.subject.keywordPlusVAPOR PERMEATION-
dc.subject.keywordPlusSECONDARY GROWTH-
dc.subject.keywordPlusMFI MEMBRANES-
dc.subject.keywordPlusPERVAPORATION DEHYDRATION-
dc.subject.keywordAuthorLTA zeolite membrane-
dc.subject.keywordAuthorCapillary tube-
dc.subject.keywordAuthorSecondary growth-
dc.subject.keywordAuthorPervaporation-
dc.subject.keywordAuthorH 2 O-
dc.subject.keywordAuthorisopropanol-
dc.subject.keywordAuthorepichlorohydrin separation-
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