Samarium(II) iodide-promoted reactions of 2,3-epoxycycloalkanone hydrazones

Title
Samarium(II) iodide-promoted reactions of 2,3-epoxycycloalkanone hydrazones
Authors
강한영홍우상이상학최경일고훈영
Keywords
samarium
Issue Date
1997-01
Publisher
Synlett.
Citation
VOL 1, 33-34
Abstract
The reaction of hydrazones of 2,3-epoxycycloalkanone promoted by samarium(II) iodide has been investigated to study the behavior of the compounds containing C=N bonds in the presence of this powerful single-electron transfer reagent. For the hydrazones derived from 2,3-epoxycyclopentanone and 2,3-epoxycyclohexanone, 3-iodo-2-cycloalkenols were isolated while the corresponding 2-cycloalkenols were the products when the hydrazones from 2,3-epoxycycloheptanone and 2,3-epoxycyclooctanone were reacted.
URI
http://pubs.kist.re.kr/handle/201004/12092
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