Samarium(II) iodide-promoted reactions of 2,3-epoxycycloalkanone hydrazones
- Samarium(II) iodide-promoted reactions of 2,3-epoxycycloalkanone hydrazones
- 강한영; 홍우상; 이상학; 최경일; 고훈영
- Issue Date
- VOL 1, 33-34
- The reaction of hydrazones of 2,3-epoxycycloalkanone promoted by samarium(II) iodide has been investigated to study the behavior of the compounds containing C=N bonds in the presence of this powerful single-electron transfer reagent. For the hydrazones derived from 2,3-epoxycyclopentanone and 2,3-epoxycyclohexanone, 3-iodo-2-cycloalkenols were isolated while the corresponding 2-cycloalkenols were the products when the hydrazones from 2,3-epoxycycloheptanone and 2,3-epoxycyclooctanone were reacted.
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