Oxido-peroxido W(VI)-histidine-MgAl-layered double hydroxide composite as an efficient catalyst in sulfide oxidation

Authors
Nikkhoo, MohammadAmini, MojtabaMorteza, S.Farnia, F.Bayrami, ArshadBagherzadeh, MojtabaGautam, SanjeevChae, Keun Hwa
Issue Date
2018-06
Publisher
WILEY
Citation
APPLIED ORGANOMETALLIC CHEMISTRY, v.32, no.6
Abstract
Oxido-peroxido W(VI)-histidine-MgAl-layered double hydroxide composite was prepared by using MgAl-layered double hydroxide as a host and oxido-peroxido W(VI)-histidine complex as a guest. The composite was characterized by XRD, IR, EDX,SEM and TEM techniques. This composite is tested for catalytic selective sulfoxidation reactions using hydrogen peroxide as oxidant showing good to moderate conversion along with high selectivity.
Keywords
LAYERED DOUBLE HYDROXIDE; MOLYBDENUM(VI) COMPLEXES; OXOPEROXO MOLYBDENUM(VI); TUNGSTEN(VI) COMPLEXES; HYDROGEN-PEROXIDE; TERMINAL OXIDANT; LIGAND SYNTHESIS; X-RAY; EPOXIDATION; OLEFINS; LAYERED DOUBLE HYDROXIDE; MOLYBDENUM(VI) COMPLEXES; OXOPEROXO MOLYBDENUM(VI); TUNGSTEN(VI) COMPLEXES; HYDROGEN-PEROXIDE; TERMINAL OXIDANT; LIGAND SYNTHESIS; X-RAY; EPOXIDATION; OLEFINS; LDH; oxidation; oxido-peroxido; sulfide; tungsten
ISSN
0268-2605
URI
https://pubs.kist.re.kr/handle/201004/121317
DOI
10.1002/aoc.4358
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KIST Article > 2018
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