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dc.contributor.authorSuh, Young-Ger-
dc.contributor.authorLim, Changjin-
dc.contributor.authorSim, Jaehoon-
dc.contributor.authorLee, Jae Kyun-
dc.contributor.authorSurh, Young-Joon-
dc.contributor.authorPaek, Seung-Mann-
dc.date.accessioned2024-01-20T02:03:53Z-
dc.date.available2024-01-20T02:03:53Z-
dc.date.created2021-09-01-
dc.date.issued2017-02-03-
dc.identifier.issn0022-3263-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/123076-
dc.description.abstractA divergent synthetic methodology for a tabernaemontanine-related alkaloid was developed. The synthetic route features practical improvements in the Pictet-Spengler cyclization for the tetrahydro-fi-carboline intermediate and an unprecedented tandem Reformatsky aza-Claisen rearrangement to create the core carbon skeleton and stereochemistries of tabernaemontanine-related alkaloids.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectENANTIOSPECIFIC TOTAL-SYNTHESIS-
dc.subjectINDOLE ALKALOIDS-
dc.subjectBISINDOLE ALKALOIDS-
dc.subjectTABEMAEMONTANA-
dc.subjectVOBASINE-
dc.titleConstruction of the Azacyclic Core of Tabernaemontanine-Related Alkaloids via Tandem Reformatsky Aza-Claisen Rearrangement-
dc.typeArticle-
dc.identifier.doi10.1021/acs.joc.6b02648-
dc.description.journalClass1-
dc.identifier.bibliographicCitationJOURNAL OF ORGANIC CHEMISTRY, v.82, no.3, pp.1464 - 1470-
dc.citation.titleJOURNAL OF ORGANIC CHEMISTRY-
dc.citation.volume82-
dc.citation.number3-
dc.citation.startPage1464-
dc.citation.endPage1470-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000394472900018-
dc.identifier.scopusid2-s2.0-85011319815-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusENANTIOSPECIFIC TOTAL-SYNTHESIS-
dc.subject.keywordPlusINDOLE ALKALOIDS-
dc.subject.keywordPlusBISINDOLE ALKALOIDS-
dc.subject.keywordPlusTABEMAEMONTANA-
dc.subject.keywordPlusVOBASINE-
dc.subject.keywordAuthorPictet-Spengler cyclization-
dc.subject.keywordAuthorcarbon skeleton and stereochemistries-
dc.subject.keywordAuthorX-ray crystallographic structure-
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