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dc.contributor.authorKim, Yoonyoung-
dc.contributor.authorLee, Eung-Kyu-
dc.contributor.authorShim, Jae-Hyeok-
dc.contributor.authorCho, Young Whan-
dc.contributor.authorYoon, Kyung Byung-
dc.date.accessioned2024-01-21T02:30:43Z-
dc.date.available2024-01-21T02:30:43Z-
dc.date.created2021-09-01-
dc.date.issued2006-09-28-
dc.identifier.issn0925-8388-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/135105-
dc.description.abstractMagnesium alanate Mg(AlH4)(2) has been synthesized by mechanochemically activated metathesis reaction between NaAlH4 and MgCl2 without solvent, this metathesis reaction proceeded completely. The thermal decomposition behavior of solvent-free Mg(AlH4)(2) has been analyzed by TG/MS and DSC. It has been confirmed that Mg(AlH4)(2) decomposes in two steps: the first decomposition reaction Mg(AlH4)(2) -> MgH2 + 2Al + 3H(2) is exothermic and starts at about 115 degrees C. The second one MgH2 + 2Al -> 1/2Al(3)Mg(2) + 1/2Al + H-2 is endothermic in total and starts at about 240 degrees C, although the formation reaction of Al3Mg2 (3Al + 2Mg -> Al3Mg2) is exothermic. (c) 2005 Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.publisherELSEVIER SCIENCE SA-
dc.subjectALUMINUM HYDRIDES-
dc.subjectMAGNESIUM ALANATE-
dc.subjectX-RAY-
dc.subjectACTIVATION-
dc.subjectLITHIUM-
dc.titleMechanochemical synthesis and thermal decomposition of Mg(AlH4)(2)-
dc.typeArticle-
dc.identifier.doi10.1016/j.jallcom.2005.11.063-
dc.description.journalClass1-
dc.identifier.bibliographicCitationJOURNAL OF ALLOYS AND COMPOUNDS, v.422, no.1-2, pp.283 - 287-
dc.citation.titleJOURNAL OF ALLOYS AND COMPOUNDS-
dc.citation.volume422-
dc.citation.number1-2-
dc.citation.startPage283-
dc.citation.endPage287-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000240579500051-
dc.identifier.scopusid2-s2.0-33747802749-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalWebOfScienceCategoryMaterials Science, Multidisciplinary-
dc.relation.journalWebOfScienceCategoryMetallurgy & Metallurgical Engineering-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaMaterials Science-
dc.relation.journalResearchAreaMetallurgy & Metallurgical Engineering-
dc.type.docTypeArticle-
dc.subject.keywordPlusALUMINUM HYDRIDES-
dc.subject.keywordPlusMAGNESIUM ALANATE-
dc.subject.keywordPlusX-RAY-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusLITHIUM-
dc.subject.keywordAuthormagnesium alanate-
dc.subject.keywordAuthorcomplex metal hydride-
dc.subject.keywordAuthorhydrogen storage material-
dc.subject.keywordAuthorthermal decomposition-
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