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dc.contributor.authorTripathi, A-
dc.contributor.authorParise, JB-
dc.contributor.authorKim, SJ-
dc.contributor.authorLee, Y-
dc.contributor.authorJohnson, GM-
dc.contributor.authorUh, YS-
dc.date.accessioned2024-01-21T13:09:38Z-
dc.date.available2024-01-21T13:09:38Z-
dc.date.created2021-09-04-
dc.date.issued2000-12-
dc.identifier.issn0897-4756-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/140916-
dc.description.abstractTwo new aluminogermanates, K-AlGe-GIS (K8Al8Ge8O32. 8H(2)O) and Na-AlGe-GIS (Na24Al24Ge24O96. 40H(2)O), with the zeolite gismondine (GIS) type framework topology have been synthesized hydrothermally and characterized using single-crystal X-ray diffraction. K-AlGe-GIS crystallizes in the monoclinic space group I2/a with a = 10.311(2) Angstrom, b = 9.749(1) Angstrom, c = 10.225(6) Angstrom, beta = 90.000(2)degrees, and Z = 8. Na-AlGe-GIS crystallizes in the monoclinic space group C2/c with a = 14.490(3) Angstrom, b = 9.940(2) Angstrom, c = 23.530(5) Angstrom, beta = 105.90(3)degrees, and Z = 8. Strict alternation of Ge and Al atoms over the framework sites lowers the symmetry of these aluminogermanates from their topological framework symmetry of I4(1)/amd to the real symmetry I2/a. Both structures consist of twisted double-crankshaft chains running along the a and c axes. In K-AlGe-GIS, potassium and water statistically occupy extraframework sites along the perpendicular eight-ring channels, In Na-AlGe-GIS, all three sodium sites are fully occupied and only three out of seven sites containing water are statistically occupied. A zigzag-ordered arrangement of Na sites in Na-AlGe-GIS results in unit cell symmetry hitherto unobserved for GIS. The synthesis of Na-AlGe-GIS requires the presence of organic bases, while K-AlGe-GIS can be synthesized from gels with or without organic bases. Time-resolved synchrotron X-ray powder di fraction patterns obtained as a function of temperature for Na-AlGe-GIS show a gradual disappearance of the C-centered cell between 150 and 180 degreesC with a simultaneous appearance of an I-centered monoclinic phase. Calculated powder diffraction patterns indicate that this phase change results from disordering of Na sites in the eight-ring channels. Results of a single-crystal diffraction study for a 50% Na-exchanged K-AlGe-GIS (K4Na4Al8Ge8O32. 8H(2)O) shows that the space group I2/a is retained with a 0.3% increase in the unit cell volume. Both the AlGe frameworks retain the GIS topology until ca. 150 degreesC after dehydration. The average Al-O-Ge (T-O-T) bond angle of 135.75 degrees in K-AlGe-GIS and 135.29 degrees in Na-AlGe-GIS is smaller than the average Al-O-Si bond angle of 145 degrees in aluminosilicates.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectRIETVELD REFINEMENT-
dc.subjectPOWDER DIFFRACTION-
dc.subjectCRYSTAL-STRUCTURE-
dc.subjectRHO TOPOLOGY-
dc.subjectEXCHANGE-
dc.titleStructural changes and cation site ordering in Na and K forms of aluminogermanates with the zeolite gismondine topology-
dc.typeArticle-
dc.identifier.doi10.1021/cm000459s-
dc.description.journalClass1-
dc.identifier.bibliographicCitationCHEMISTRY OF MATERIALS, v.12, no.12, pp.3760 - 3769-
dc.citation.titleCHEMISTRY OF MATERIALS-
dc.citation.volume12-
dc.citation.number12-
dc.citation.startPage3760-
dc.citation.endPage3769-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000166073600035-
dc.identifier.scopusid2-s2.0-0034507270-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalWebOfScienceCategoryMaterials Science, Multidisciplinary-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaMaterials Science-
dc.type.docTypeArticle-
dc.subject.keywordPlusRIETVELD REFINEMENT-
dc.subject.keywordPlusPOWDER DIFFRACTION-
dc.subject.keywordPlusCRYSTAL-STRUCTURE-
dc.subject.keywordPlusRHO TOPOLOGY-
dc.subject.keywordPlusEXCHANGE-
dc.subject.keywordAuthorzeolite-
dc.subject.keywordAuthoraluminogermanate-
dc.subject.keywordAuthorgismondine-
dc.subject.keywordAuthorcation site-
dc.subject.keywordAuthortopoloygy-
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KIST Article > 2000
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