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Synthesis of 1,3-diketones by reaction of alpha-haloketones with acyl cyanides promoted by samarium diiodide

Authors
Baek, HS; 유병우; Keum, SR; Yoon, CM; Kim, SH; Kim, JH
Issue Date
2000-01
Publisher
MARCEL DEKKER INC
Citation
SYNTHETIC COMMUNICATIONS, v.30, no.1, pp.31 - 38
Abstract
alpha-Haloketones reacted with acyl cyanides to form 1,3-diketones in the presence of samarium diiodide. The reaction was assumed to proceed:via a mechanism involving samarium enolates formed in situ from alpha -haloketones.
Keywords
ALDOL-TYPE REACTION; ORGANIC-SYNTHESIS; FACILE SYNTHESIS; ACID-CHLORIDES; HALO KETONES; TRIIODIDE; IODIDE; ROUTE; SMI2; samarium diiodie; 1,3-diketone; α-haloketone; acylcyanide
ISSN
0039-7911
URI
https://pubs.kist.re.kr/handle/201004/141693
DOI
10.1080/00397910008087289
Appears in Collections:
KIST Article > 2000
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