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dc.contributor.authorLEE, YA-
dc.contributor.authorHONG, JK-
dc.contributor.authorJUNG, OS-
dc.contributor.authorSOHN, YS-
dc.date.accessioned2024-01-21T21:34:14Z-
dc.date.available2024-01-21T21:34:14Z-
dc.date.created2022-01-10-
dc.date.issued1994-08-20-
dc.identifier.issn0253-2964-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/145526-
dc.description.abstractCoordination isomers of cis-(N-N)Pt(Glu) prepared by reaction of cis-(N-N)Pt(SO4) (N-N=2NH(3). ethylenediamine(en), (R,R)-1,2-diaminocyclohexane (DACH), N,N,N',N'-tetramethylethylenediamine (TMEDA)) with barium glutamate in water have been monitored and characterized by H-1-NMR,C-13-NMR, IR, and mass spectra. The reaction at room temperature affords the mixture of O,O'- and N,alpha O-chelated platinum(II) complexes. The O,O'-chelate initially formed isomerized to N,alpha O-chelate on standing for a long time or increasing temperature. The ratio of the two isomers at room temperature depends on the nature of the nitrogen donor coligand (N-N).-
dc.languageEnglish-
dc.publisherKOREAN CHEMICAL SOC-
dc.subjectCIS-DIAMMINEDIAQUAPLATINUM(II) CATION-
dc.subjectPLATINUM(II) COMPLEXES-
dc.subjectPT-195-
dc.subjectN-15-
dc.subjectCIS-DICHLORODIAMMINEPLATINUM(II)-
dc.subject(METHYLIMINO)DIACETATE-
dc.subjectIMINODIACETATE-
dc.subjectC-13-
dc.titleDIAMINOPLATINUM(II) COMPLEXES OF GLUTAMIC-ACID - OBVIOUS CHELATING ISOMERIZATION-
dc.typeArticle-
dc.description.journalClass1-
dc.identifier.bibliographicCitationBULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.15, no.8, pp.669 - 673-
dc.citation.titleBULLETIN OF THE KOREAN CHEMICAL SOCIETY-
dc.citation.volume15-
dc.citation.number8-
dc.citation.startPage669-
dc.citation.endPage673-
dc.description.journalRegisteredClassscie-
dc.identifier.wosidA1994PE49400018-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusCIS-DIAMMINEDIAQUAPLATINUM(II) CATION-
dc.subject.keywordPlusPLATINUM(II) COMPLEXES-
dc.subject.keywordPlusPT-195-
dc.subject.keywordPlusN-15-
dc.subject.keywordPlusCIS-DICHLORODIAMMINEPLATINUM(II)-
dc.subject.keywordPlus(METHYLIMINO)DIACETATE-
dc.subject.keywordPlusIMINODIACETATE-
dc.subject.keywordPlusC-13-
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