Full metadata record
DC Field | Value | Language |
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dc.contributor.author | LEE, YA | - |
dc.contributor.author | HONG, JK | - |
dc.contributor.author | JUNG, OS | - |
dc.contributor.author | SOHN, YS | - |
dc.date.accessioned | 2024-01-21T21:34:14Z | - |
dc.date.available | 2024-01-21T21:34:14Z | - |
dc.date.created | 2022-01-10 | - |
dc.date.issued | 1994-08-20 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | https://pubs.kist.re.kr/handle/201004/145526 | - |
dc.description.abstract | Coordination isomers of cis-(N-N)Pt(Glu) prepared by reaction of cis-(N-N)Pt(SO4) (N-N=2NH(3). ethylenediamine(en), (R,R)-1,2-diaminocyclohexane (DACH), N,N,N',N'-tetramethylethylenediamine (TMEDA)) with barium glutamate in water have been monitored and characterized by H-1-NMR,C-13-NMR, IR, and mass spectra. The reaction at room temperature affords the mixture of O,O'- and N,alpha O-chelated platinum(II) complexes. The O,O'-chelate initially formed isomerized to N,alpha O-chelate on standing for a long time or increasing temperature. The ratio of the two isomers at room temperature depends on the nature of the nitrogen donor coligand (N-N). | - |
dc.language | English | - |
dc.publisher | KOREAN CHEMICAL SOC | - |
dc.subject | CIS-DIAMMINEDIAQUAPLATINUM(II) CATION | - |
dc.subject | PLATINUM(II) COMPLEXES | - |
dc.subject | PT-195 | - |
dc.subject | N-15 | - |
dc.subject | CIS-DICHLORODIAMMINEPLATINUM(II) | - |
dc.subject | (METHYLIMINO)DIACETATE | - |
dc.subject | IMINODIACETATE | - |
dc.subject | C-13 | - |
dc.title | DIAMINOPLATINUM(II) COMPLEXES OF GLUTAMIC-ACID - OBVIOUS CHELATING ISOMERIZATION | - |
dc.type | Article | - |
dc.description.journalClass | 1 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.15, no.8, pp.669 - 673 | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 15 | - |
dc.citation.number | 8 | - |
dc.citation.startPage | 669 | - |
dc.citation.endPage | 673 | - |
dc.description.journalRegisteredClass | scie | - |
dc.identifier.wosid | A1994PE49400018 | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | CIS-DIAMMINEDIAQUAPLATINUM(II) CATION | - |
dc.subject.keywordPlus | PLATINUM(II) COMPLEXES | - |
dc.subject.keywordPlus | PT-195 | - |
dc.subject.keywordPlus | N-15 | - |
dc.subject.keywordPlus | CIS-DICHLORODIAMMINEPLATINUM(II) | - |
dc.subject.keywordPlus | (METHYLIMINO)DIACETATE | - |
dc.subject.keywordPlus | IMINODIACETATE | - |
dc.subject.keywordPlus | C-13 | - |
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