Facile One-Pot Synthesis of 1-Alkyl-3-polyfluoroalkyl Imidazolium Ionic Liquids
- Facile One-Pot Synthesis of 1-Alkyl-3-polyfluoroalkyl Imidazolium Ionic Liquids
- 김동섭; 데비; 뉴엔딘콴; 서동진; 김홍곤; 김훈식; 이현주
- ionic liquids; imidazolium; fluorine; fluoroolefin; hydroamination
- Issue Date
- VOL 13, 2101-2104
- Abstract: Imidazolium-based ionic liquids bearing a polyfluorinated
alkyl group on the cation were efficiently synthesized in excellent
yields and selectivities from the one-pot reaction of a
fluoroolefin with [1-alkyl-3H-imidazolium]X, where X = Cl, NO3,
CF3CO2, BF4 or (CF3SO2)2N, formed in situ from the interaction of
an alkylimidazole with an acid, HX.
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