Preparation of Potassium Azidoaryltrifluoroborates and Their Cross-Coupling with Aryl Halides

Title
Preparation of Potassium Azidoaryltrifluoroborates and Their Cross-Coupling with Aryl Halides
Authors
조영애김동수안홍열Belgin CanturkGary A. Molander함정엽
Keywords
Organotrifluoroborate; haloaryltrifluoroborate; Azidoaryltrifluoroborate; Cross-Coupling
Issue Date
2009-10
Publisher
Organic letters
Citation
VOL 11, NO 19, 4330-4333
Abstract
Potassium azidoaryltrifluoroborates have been prepared from the corresponding haloaryltrifluoroborates in 73-98% yields. Also, we successfully cross-coupled the azido-functionalized organotrifluoroborates and carried out a one-pot sequential cross-coupling/1,3-dipolar cycloaddition and a one-pot cross-coupling/azide reduction process.
URI
http://pubs.kist.re.kr/handle/201004/35925
ISSN
1523-7060
Appears in Collections:
KIST Publication > Article
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