Unusual anion effects on the solution-behavior of cyclodimeric Pd(II) complex

Title
Unusual anion effects on the solution-behavior of cyclodimeric Pd(II) complex
Authors
류윤경김초롱노태환이재균정옥상
Keywords
Anion exchange; Anion effects; Cyclodimer; Palladium(II) complex
Issue Date
2009-11
Publisher
Journal of molecular structure
Citation
VOL 938, 20-23
Abstract
Unusual anion effects on the solution-behavior of [(dppp)Pd(m-ptms)]2(X)4 (dppp = 1,3-bis(diphenylphosphino)propane; m-ptms = 1,3-bis(3-pyridyl)tetramethyldisiloxane; X- = CF3SO3-, PF6-, ClO4-, and NO3-), based on the 1H NMR chemical shifts and conductivity, were observed. The fluxionality of the cyclodimeric skeleton was found to be sensitive to the Hoffmeister series of anions.
URI
http://pubs.kist.re.kr/handle/201004/36667
ISSN
0022-2860
Appears in Collections:
KIST Publication > Article
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