Oxidation of Chloroform in a Gliding-Arc Plasma: Observation of Molecular Vibrations

Title
Oxidation of Chloroform in a Gliding-Arc Plasma: Observation of Molecular Vibrations
Authors
Antonius Indarto최재욱이화웅
Keywords
Ab initio calculation; chloroform oxidation; gliding-arc plasma; molecular vibration
Issue Date
2009-08
Publisher
IEEE transactions on plasma science
Citation
VOL 37, NO 8, 1526-1531
Abstract
This paper presents a direct comparison of the vibrational spectra between quantum mechanistic calculation and ultrashort laser pulses (USLP) spectrometer for chloroform oxidation. The chloroform decomposition was conducted in the presence of oxygen by using a gliding-arc plasma. In agreement with the prediction from both ab initio density functional theory calculation and USLP spectra analysis, it shows that the early step of the chloroform decomposition by oxygen follows a mechanism of CHCl3 + O2 → CCl3OOH → COCl2 + OH + Cl.
URI
http://pubs.kist.re.kr/handle/201004/37004
ISSN
0093-3813
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