Simultaneous determination of 1,4-Dioxane and Formaldehyde in water by solid phase microextraction gas chromatography-time of flight mass spectrometry

Title
Simultaneous determination of 1,4-Dioxane and Formaldehyde in water by solid phase microextraction gas chromatography-time of flight mass spectrometry
Authors
박현미와나디문동주조양하이연희이강봉
Keywords
formaldehyde; 1,4-dioxane; water
Issue Date
2011-11
Publisher
RAFA 2011
Abstract
Simultaneous determination of 1,4-dioxane and formaldehyde in water by solid phase microextraction (SPME)-gas chromatography–time of flight mass spectrometer (GC-TOFMS) was investigated. Two types of SPME fibers, polydimethylsiloxane (PDMS)/divinylbenzene(DVB) and 100 μm–polydimethylsiloxane (PDMS) were investigated. The aim of this study was to develop a method that allows the determination of 1,4-dioxane and formaldehyde simultaneously. Before the direct SPME extraction, 0.3 w/v % of 2,4-dinitrophenylhydrazine was used as a derivatizing agent for the analysis of formaldehyde. Three extraction parameters (extraction time, temperature, and salting effect) were observed. PDMS/DVB fiber was found to give the better response. Optimum extraction condition was found at 30oC for 15 min in 5% NaCl solution. The method showed a linear correlation (R2>0.99) in the calibration range of 0.03 – 3.33 μg/ml for 1,4-dioxane and 0.03 – 1.67 ng/ml for formaldehyde.
URI
http://pubs.kist.re.kr/handle/201004/38109
Appears in Collections:
KIST Publication > Conference Paper
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