Hydrogen Production from Steam Reforming of n-hexadecane over Ni-based Hydrotalcite-like Catalyst
- Hydrogen Production from Steam Reforming of n-hexadecane over Ni-based Hydrotalcite-like Catalyst
- 이승환; 문동주
- Diesel steam reforming; Hydrotalcite; Hydrogen production; spc-Ni/MgAl catalyst; *2010기관고유평가에 반영 완료
- Issue Date
- 한국수소 및 신에너지학회논문집
- VOL 21, NO 5, ?-?
- Steam reforming of n-hexadecane, a major component of diesel over Ni-based hydrotalcite-like catalyst
was carried out at 900℃ at atmospheric pressure with space velocity of 10,000h-1 and feed molar ratio of
steam/carbon=3.0. Ni-based hydrotalcite catalyst was prepared by a solid phase crystallization (spc) method
and characterized by N2-physisorption, CO chemisorption, TPR, XRD, and TEM techniques. It was found
that spc–Ni/MgAl catalyst showed higher catalytic stability and inhibition of carbon formation than Ni/γ
-Al2O3 catalyst under the tested conditions. The results suggest that the modified spc-Ni/MgAl catalyst after
optimization may be applied for the SR reaction of diesel.
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