Functionalization of Organotrifluoroborates via Cu-Catalyzed C-N Coupling Reaction

Title
Functionalization of Organotrifluoroborates via Cu-Catalyzed C-N Coupling Reaction
Authors
이정현김희진김태정송중호김원석함정엽
Keywords
Organotrifluoroborate; Potassium N-heterobiaryltrifluoroborates; Cu-catalyzed C-N coupling; Chan-Lam coupling; N-Heterobiarene
Issue Date
2013-01
Publisher
Bulletin of the Korean Chemical Society
Citation
VOL 34, NO 1, 42-48
Abstract
Potassium N-heterobiaryltrifluoroborates were successfully prepared via a selective Cu-catalyzed C-N coupling reaction. The BF3K moiety was well tolerated under the reaction conditions involving CuI and dimethylethylenediamine (DMEDA) in the presence of DMSO. The Pd-catalyzed Suzuki-Miyaura cross couplings of potassium N-heterobiaryltrifluoroborates with bromoarenes were studied to prepare the N-heterotriaryl compounds. Moreover, homocoupling, iodination, and hydroxylation of potassium N-heterobiaryltrifluoroborates provided the corresponding products in high yields.
URI
http://pubs.kist.re.kr/handle/201004/44519
ISSN
02532964
Appears in Collections:
KIST Publication > Article
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE