Sintering behavior and dielectric properties of KCa2Nb3O10 ceramics

Title
Sintering behavior and dielectric properties of KCa2Nb3O10 ceramics
Authors
권상효임미르한귀팡김진성남산최지원황성주
Keywords
Dielectric; Layered perovskite; Low loss; Multilayer ceramic capacitor
Issue Date
2013-05
Publisher
Journal of the European Ceramic Society
Citation
VOL 33, NO 5, 907-911
Abstract
Dense KCa2Nb3O10 (KCN) oxides were synthesized and their dielectric properties were investigated. A homogeneous KCN phase was formed in the specimen sintered above 1300 ◦C, but a CaNb2O6 secondary phase was developed in the specimen sintered at 1400 ◦C, as result of the evaporation of K2O. The KCN oxides sintered at 1375 ◦C showed a high relative density that was 97.1% of the theoretical density. Furthermore, liquid-phase-assisted abnormal grain growth occurred during sintering. The dielectric constant of this KCN oxide was 46, with a low dielectric loss of 0.9% at 100 kHz; these values are smaller than those that were previously reported. Complex impedance analysis indicated that the resistivity of the KCN oxide was very low, probably as a result of the presence of K+ ions between the layers, and this could be the origin of the low-frequency dispersion of the KCN oxides.
URI
http://pubs.kist.re.kr/handle/201004/44555
ISSN
09552219
Appears in Collections:
KIST Publication > Article
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