Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?

Title
Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?
Authors
Yigang YanArndt RemhofDaniel Rentsch이영수조영환Andreas Zuttel
Issue Date
2013-06
Publisher
Chemical communications
Citation
VOL 49, NO 45, 5234-5236
Abstract
Dodecaborates, i.e. the [B12H12]2- containing species, are often observed as main intermediates in the hydrogen sorption cycle of metal borohydrides, hindering rehydrogenation. In the decomposition process of Y(BH4)3, yttrium octahydrotriborate, i.e. Y(B3H8)3, rather than the stable Y2(B12H12)3, is formed as the main intermediate.
URI
http://pubs.kist.re.kr/handle/201004/44871
ISSN
13597345
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KIST Publication > Article
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