A Kinetic study of the decross-linking of cross-linked polyethylene in supercritical methanol

Title
A Kinetic study of the decross-linking of cross-linked polyethylene in supercritical methanol
Authors
이홍식정주형조항규구종민홍순만김화용이윤우
Keywords
kinetic; crosslinking; supercritical fluid; Cross-linked polyethylene; Supercritical methanol; Decross-linking; Recycling
Issue Date
2008-12
Publisher
Polymer degradation and stability
Citation
VOL 93, NO 12, 2084-2088
Abstract
The recycling of cross-linked polyethylene (XLPE) by a decross-linking reaction in supercritical methanol was studied using a batch reactor. XLPEs with initial gel contents of 45, 55 and 65% were employed and subjected to reaction temperatures between 320 and 360 °C. Complete decross-linking of XLPE was achieved in 10 min in supercritical methanol at 360 °C and 15 MPa. For the first time, chemical kinetics for the decross-linking reaction is proposed based on the gel concentration, and applicable to the reactor design. With respect to the gel concentration, the first-order reaction model agreed well with the experimental results. The evaluated kinetic constant was 0.0867 ± 0.0082 cm3/mg min at 350 °C, and the activation energy was 578 ± 25 kJ/mol.
URI
http://pubs.kist.re.kr/handle/201004/45549
ISSN
0141-3910
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KIST Publication > Article
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