Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B&#8722

Title
Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B− H Activation

Title
H Activation
Authors
김성관한원식김태진김태영남석우Mariusz MitorajŁukasz PiekosArtur MichalakSon-Jong Hwang강상욱
Keywords
ammonia borane; dehydrogenation; Pd(II) complexes
Issue Date
2010-07
Publisher
Journal of the American Chemical Society
Citation
VOL 132, NO 29, 9954-9955
Abstract
Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.
URI
http://pubs.kist.re.kr/handle/201004/45576
ISSN
0002-7863
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KIST Publication > Article
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