Cocktails of Paste Coatings for Performance Enhancement of CuInGaS2 Thin-Film Solar Cells

Title
Cocktails of Paste Coatings for Performance Enhancement of CuInGaS2 Thin-Film Solar Cells
Authors
안희상조윤애박세진전효상황윤정김동욱민병권
Keywords
CIGS; solar cells; paste coating; chalcopyrite; solution process; sulfurization
Issue Date
2014-01
Publisher
ACS Applied Materials & Interfaces
Citation
VOL 6, NO 2, 888-893
Abstract
To fabricate low-cost and printable wide-bandgap CuInxGa1−xS2 (CIGS) thin-film solar cells, a method based on a precursor solution was developed. In particular, under this method, multiple coatings with two pastes with different properties (e.g., viscosity) because of the different binder materials added were applied. Paste A could form a thin, dense layer enabling a high-efficiency solar cell but required several coating and drying cycles for the desired film thickness. On the other hand, paste B could easily form onemicrometer-thick films by means of a one-time spin-coating process but the porous microstructure limited the solar cell performance. Three different configurations of the CIGS films (A + B, B + A, and A + B + A) were realized by multiple coatings with the two pastes to find the optimal stacking configuration for a combination of the advantages of each paste. Solar cell devices using these films showed a notable difference in their photovoltaic characteristics. The bottom dense layer increased the minority carrier diffusion length and enhanced the short-circuit current. The top dense layer could suppress interface recombination but exhibited a low optical absorption, thereby decreasing the photocurrent. As a result, the A + B configuration could be suggested as a desirable simple stacking structure. The solar cell with A + B coating showed a highly improved efficiency (4.66%) compared to the cell with a film prepared by paste B only (2.90%), achieved by simple insertion of a single thin (200 nm), dense layer between the Mo back contact and a thick porous CIGS layer.
URI
http://pubs.kist.re.kr/handle/201004/47124
ISSN
19448244
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KIST Publication > Article
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