Cascade of Liquid-Phase Catalytic Transfer Hydrogenation and Etherification of 5-Hydroxymethylfurfural to Potential Biodiesel Components over Lewis Acid Zeolites

Title
Cascade of Liquid-Phase Catalytic Transfer Hydrogenation and Etherification of 5-Hydroxymethylfurfural to Potential Biodiesel Components over Lewis Acid Zeolites
Authors
제정호Eyas MahmoudRaul F. LoboDionisios G. Vlachos
Keywords
alcohols; biomass; etherification; transfer hydrogenation; zeolites
Issue Date
2014-02
Publisher
ChemCatChem
Citation
VOL 6, NO 2, 508-513
Abstract
We report a one-step process for the production of diesel fuel from biomass-derived 5-hydroxymethylfurfural (HMF). The reaction proceeds through the sequential transfer hydrogenation and etherification of HMF to 2,5-bis(alkoxymethyl)furan, a potential biodiesel additive, catalyzed by a Lewis acid zeolite, such as Sn-Beta or Zr-Beta. An alcohol is used as a hydrogen donor and as a reactant in etherification. This cascade reaction can selectively produce high yields of the biodiesel additive (>80% yield) from HMF with the Sn-Beta catalyst and secondary alcohols, such as 2-propanol and 2-butanol.
URI
http://pubs.kist.re.kr/handle/201004/47171
ISSN
18673880
Appears in Collections:
KIST Publication > Article
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