Water is a key factor to alter the structure and electrochemical properties of carboxylate-bridged dimanganese(II) complexes

Title
Water is a key factor to alter the structure and electrochemical properties of carboxylate-bridged dimanganese(II) complexes
Authors
Dharmalingam SivanesanSethuraman KannanThangaian Daniel Thangadurai정광덕윤성호
Keywords
Water splitting; electrochemical properties; Mn complex
Issue Date
2014-08
Publisher
Dalton transactions
Citation
VOL 43, NO 30, 11465-11469
Abstract
The synthesis and physical properties of dimanganese(II) compounds with varying numbers of water ligands housed in the four bulky carboxylate motifs, including the first complex with a parallelogram core {Mn2(μ-OH2)2(μ-O2CR)}3+ unit, are described. The isolation of these complexes revealed how water could alter the structural and electrochemical properties of similar carboxylate-bridged dimanganese(II) cores that may occur in a variety of active sites of Mn-containing metalloenzymes. These studies support the notion that water molecules in coordination spheres of active sites of metalloproteins are not a simple spectator medium but the modulation factor of structures and functions.
URI
http://pubs.kist.re.kr/handle/201004/47744
ISSN
14779226
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KIST Publication > Article
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