Optical Properties of Amorphous Ge1-xSex and Ge1-x-ySexAsy Thin Films - Optical Gap Bowing and Phonon Modes

Title
Optical Properties of Amorphous Ge1-xSex and Ge1-x-ySexAsy Thin Films - Optical Gap Bowing and Phonon Modes
Authors
Ho Suk LeeHyeon Seob SoHosun LeeHae-Young ShinSeokhyun Yoon안형우김수동이수연정두석정병기
Keywords
chalcogenide glass; dielectric function; optical gap energy; Urbach energy; Phonon mode
Issue Date
2014-06
Publisher
Journal of the Korean Physical Society
Citation
VOL 64, NO 11, 1726-1736
Abstract
We investigated the optical properties of Ge1−xSex and Ge1−x−ySexAsy amorphous films by using spectroscopic ellipsometry and Raman spectroscopy. The dielectric functions and absorption coefficients (α) of the amorphous films were determined from the measured ellipsometric angles (Ψ,Δ). We obtained the optical gap energies and the Urbach energies from the absorption coefficients and found a strong bowing effect in the optical gap energy of Ge1−x−ySexAsy, where the endpoint binaries were Ge0.50Se0.50 and Ge0.31As0.69. Based on the correlation between the optical gap energies and the Urbach energies, we attributed the large bowing parameter to electronic disorder. Using Raman spectroscopy, we measured the phonon modes and discussed the composition dependence of the phonon peak frequencies and lineshapes in terms of structural units. Based on the composition dependence of the phonons in Ge1−x−ySexAsy, we identified the phonon modes of Ge0.31As0.69. A resonant Raman phenomenon was observed in Ge0.40Se0.60 at a laser excitation of 514 nm (2.41 eV). We verified that this laser energy corresponded to the transition energy of Ge0.40Se0.60 by using the second derivative of the dielectric function of Ge0.40Se0.60.
URI
http://pubs.kist.re.kr/handle/201004/47970
ISSN
03744884
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