Surface coating of spinel LiMn2O4 cathode electrode with lithium-nickel-manganese-oxide by RF sputtering method for lithium-ion batteries

Title
Surface coating of spinel LiMn2O4 cathode electrode with lithium-nickel-manganese-oxide by RF sputtering method for lithium-ion batteries
Authors
채유진이중기최원창
Keywords
sputtering method; spinel lithium manganese oxide; lithium-nickel-manganese-oxide; lithium-ion battery; surface modification
Issue Date
2014-09
Publisher
Journal of electroanalytical chemistry
Citation
VOL 730, 20-25
Abstract
Lithium–nickel–manganese-oxide was coated using sputtering equipment on spinel LiMn2O4 cathode electrodes prepared by a conventional tape-casting method. Surface modification of the electrodes was confirmed by field emission scanning electron microscopy and field-emission electron-probe microanalysis. Electrochemical evaluations were performed in constant current mode and the galvanostatic intermittent titration technique revealed that surface coating improved the rate capability of electrode in lithium cells. The surface-modified electrode exhibited better capacity retention and suppressed the impedance increase during the storage test at 60 °C in a fully charged state as compared to the bare electrode. Also, the lithium–nickel–manganese-oxide deposition improves the thermal stability of electrodes as confirmed by differential scanning calorimetry.
URI
http://pubs.kist.re.kr/handle/201004/48106
ISSN
15726657
Appears in Collections:
KIST Publication > Article
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