Nanoscopic management of molecular packing and orientation of small molecules by a combination of linear and branched alkyl side chains

Title
Nanoscopic management of molecular packing and orientation of small molecules by a combination of linear and branched alkyl side chains
Authors
정민우윤영운박재훈차원석김아정강진백Sanjeev Gautam서동균조정호김현정최종용채근화곽경원손해정고민재김홍곤이도권김진영최동훈김봉수
Keywords
organic semiconductors; conjugated small molecules; molecular self-assembly; molecular orientation; hole mobility; power conversion efficiency; organic field-effect transistors; organic photovoltaic cells
Issue Date
2014-06
Publisher
ACS Nano
Citation
VOL 8, NO 6, 5988-6003
Abstract
We synthesized a series of acceptor–donor–acceptor-type small molecules (SIDPP-EE, SIDPP-EO, SIDPP-OE, and SIDPP-OO) consisting of a dithienosilole (SI) electron-donating moiety and two diketopyrrolopyrrole (DPP) electron-withdrawing moieties each bearing linear n-octyl (O) and/or branched 2-ethylhexyl (E) alkyl side chains. X-ray diffraction patterns revealed that SIDPP-EE and SIDPP-EO films were highly crystalline with pronounced edge-on orientation, whereas SIDPP-OE and SIDPP-OO films were less crystalline with a radial distribution of molecular orientations. Near-edge X-ray absorption fine structure spectroscopy disclosed an edge-on orientation with a molecular backbone tilt angle of ∼22° for both SIDPP-EE and SIDPP-EO. Our analysis of the molecular packing and orientation indicated that the shorter 2-ethylhexyl groups on the SI core promote tight π–π stacking of the molecular backbone, whereas n-octyl groups on the SI core hinder close π–π stacking to some degree. Conversely, the longer linear n-octyl groups on the DPP arms facilitate close intermolecular packing via octyl–octyl interdigitation. Quantum mechanics/molecular mechanics molecular dynamics simulations determined the optimal three-dimensional positions of the flexible alkyl side chains of the SI and DPP units, which elucidates the structural cause of the molecular packing and orientation explicitly. The alkyl-chain-dependent molecular stacking significantly affected the electrical properties of the molecular films. The edge-on oriented molecules showed high hole mobilities in organic field-effect transistors, while the radially oriented molecules exhibited high photovoltaic properties in organic photovoltaic cells. These results demonstrate that appropriate positioning of alkyl side chains can modulate crystallinity and molecular orientation in SIDPP films, which ultimately have a profound impact on carrier transpor
URI
http://pubs.kist.re.kr/handle/201004/48381
ISSN
19360851
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KIST Publication > Article
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