Orthogonal Reactivity of Acyl Azides in C-H Activation: Dichotomy between C-C and C-N Amidations Based on Catalyst Systems

Title
Orthogonal Reactivity of Acyl Azides in C-H Activation: Dichotomy between C-C and C-N Amidations Based on Catalyst Systems
Authors
Kwangmin Shin류재윤Sukbok Chang
Issue Date
2014-03
Publisher
Organic letters
Citation
VOL 16, 2022-2025
Abstract
The dual reactivity of acyl azides was utilized successfully in C−H activation by the choice of catalyst systems: while selective C−C amidation was achieved under thermal Rh catalysis, a Ru catalyst was found to mediate direct C−N amidation also highly selectively. Investigations of the mechanistic dichotomy between two catalytic systems are also presented.
URI
http://pubs.kist.re.kr/handle/201004/48556
ISSN
15237060
Appears in Collections:
KIST Publication > Article
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