Orthogonal Reactivity of Acyl Azides in C-H Activation: Dichotomy between C-C and C-N Amidations Based on Catalyst Systems
- Orthogonal Reactivity of Acyl Azides in C-H Activation: Dichotomy between C-C and C-N Amidations Based on Catalyst Systems
- Kwangmin Shin; 류재윤; Sukbok Chang
- Issue Date
- Organic letters
- VOL 16, 2022-2025
- The dual reactivity of acyl azides was utilized successfully in C−H activation by the choice of catalyst systems: while selective C−C amidation was achieved under thermal Rh catalysis, a Ru catalyst was found to mediate direct C−N amidation also highly selectively. Investigations of the mechanistic dichotomy between two catalytic systems are also presented.
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