Rational molecular design of PEOlated ladder-structured polysilsesquioxane membranes for high performance CO2 removal

Title
Rational molecular design of PEOlated ladder-structured polysilsesquioxane membranes for high performance CO2 removal
Authors
박성환알버트 이성수도유성황승상이영무이정현이종석
Issue Date
2015-09
Publisher
Chemical communications
Citation
VOL 51
Abstract
Poly(methoxy(polyethyleneoxy)propyl-co-methacryloxypropyl) silsesquioxane membranes with different copolymer ratios were successfully fabricated via UV-induced crosslinking with mechanical stability. By selectively introducing polyethylene oxide (PEO) groups covalently bound to the ladder-structured polysilsesquioxane, we effectively suppressed the PEO crystallization, allowing for excellent CO2/H2 and CO2/N2 separation under single as well as mixed gas conditions.
URI
http://pubs.kist.re.kr/handle/201004/50167
ISSN
13597345
Appears in Collections:
KIST Publication > Article
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