Macroporous flexible polyvinyl alcohol lithium adsorbent foam composite prepared via surfactant blending and cryo-desiccation

Title
Macroporous flexible polyvinyl alcohol lithium adsorbent foam composite prepared via surfactant blending and cryo-desiccation
Authors
Grace M. NisolaLawrence A. LimjucoEleazer L. VivasChosel P.Lawagon박명준손호경Neha Mittal나인욱김현정욱진
Keywords
Adsorption; composite; cryo-desiccation; foam; lithium recovery; polyvinyl alcohol
Issue Date
2015-11
Publisher
Chemical engineering journal
Citation
VOL 280, NO 15, 536-548
Abstract
Macroporous polyvinyl alcohol (PVA) foam composites with high loading of uniformly distributed lithium ion sieves (LIS) were successfully fabricated and evaluated for Li+ recovery. Surfactant blending combined with cryo-desiccation effectively produced LIS/PVA foams with hierarchical porosity composed of macroand mesopores. Glutaraldehyde cross-linking rendered the LIS/PVA foams insoluble in water but exhibited high water absorbency and flexibility. Relative to the LIS powder, the foams exhibited minimal reductions in adsorption capacity (qe) and kinetic properties due to: (1) high total porosity and surface area, (2) hydrophilicity of PVA matrix, and (3) high LIS loading, which promoted particle exposure on the foam surface. These features facilitated easy convective flow of water through the matrix and allowed intimate contact between the Li+ feed source and the LIS surface. Thus, LIS/PVA foams with high loadings (200–300 wt%) exhibited meager reductions in qe (7–13%) and kinetic properties compared to the LIS powder. With LIS loading increase, Li+ selectivity of LIS/PVA foams against other cations (i.e. Na+, K+, Mg2+, Ca2+) likewise approached that of the LIS powder. While 300 wt% LIS/PVA had low mechanical property, lower LIS loadings of 200- and 250 wt% were highly durable and exhibited no deterioration in adsorption performance and reusability. Among the prepared LIS/PVA, 250 wt% demonstrated the highest adsorption performance and can be repeatedly used for long-term application. The developed LIS/PVA foams are promising Li+
URI
http://pubs.kist.re.kr/handle/201004/50713
ISSN
13858947
Appears in Collections:
KIST Publication > Article
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