Two-Dimensional Heterogeneous Ruthenium-Molybdenum Disulfide Nanocatalyst for the Selective Aerobic Oxidation of Amines

Title
Two-Dimensional Heterogeneous Ruthenium-Molybdenum Disulfide Nanocatalyst for the Selective Aerobic Oxidation of Amines
Authors
엄병헌Muhammad Asif HussainMinHo YangHyung-Seok JangSung-Yeon HwangBong Gill ChoJung Won Kim
Issue Date
2016-06
Publisher
Industrial & engineering chemistry research
Citation
VOL 55, NO 25, 7043-7047
Abstract
A highly efficient two-dimensional (2D) nanocatalyst for the aerobic oxidation of amines, consisting of ruthenium-exfoliated molybdenum disulfide (Ru@E-MoS2), was investigated. As-synthesized Ru@E-MoS2 yielded the nitriles from various aromatic, aliphatic, allylic, and heteroatomic amines with high selectivity in molecular oxygen as terminal oxidants. The Ru@E-MoS2 experienced an improved catalytic activity for benzylamine and p-substituted benzylamine derivatives and produced good turnover numbers (TONs) for aliphatic amines. Moreover, the heterogeneous Ru@E-MoS2 nanocatalyst maintained its catalytic performance for five cycles of benzylamine oxidation reaction.
URI
http://pubs.kist.re.kr/handle/201004/59924
ISSN
08885885
Appears in Collections:
KIST Publication > ETC
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