Activation of Peroxymonosulfate by Surface-Loaded Noble Metal Nanoparticles for Oxidative Degradation of Organic Compounds

Title
Activation of Peroxymonosulfate by Surface-Loaded Noble Metal Nanoparticles for Oxidative Degradation of Organic Compounds
Authors
김상훈안용윤윤은태서지원이창하김재홍이재상
Issue Date
2016-09
Publisher
Environmental science & technology
Citation
VOL 50, NO 18-10197
Abstract
This study demonstrates the capability of noble metal nanoparticles immobilized on Al2O3 or TiO2 support to effectively activate peroxymonosulfate (PMS) and degrade select organic compounds in water. The noble metals outperformed a benchmark PMS activator such as Co2+ (water-soluble) for PMS activation and organic compound degradation at acidic pH and showed the comparable activation capacity at neutral pH. The efficiency was found to depend on the type of noble metal (following the order of Pd > Pt approximate to Au >> Ag), the amount of noble metal deposited onto the support, solution pH, and the type of target organic substrate. In contrast to common PMS-activated oxidation processes that involve sulfate radical as a main oxidant, the organic compound degradation kinetics were not affected by sulfate radical scavengers and exhibited substrate dependency that resembled the PMS activated by carbon nanotubes. The results presented herein suggest that noble metals can mediate electron transfer from organic compounds to PMS to achieve persulfate-driven oxidation, rather than through reductive conversion of PMS to reactive sulfate radical.
URI
http://pubs.kist.re.kr/handle/201004/64767
ISSN
0013-936X
Appears in Collections:
KIST Publication > Article
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