Defect-induced ripening of zeolitic-imidazolate framework ZIF-8 and its implication to vapor-phase membrane synthesis
- Defect-induced ripening of zeolitic-imidazolate framework ZIF-8 and its implication to vapor-phase membrane synthesis
- 안희성; 알버트 이성수; 권혁택; 정해권; 이태희; 장은희; 이종석; 최정규
- Issue Date
- Chemical communications
- VOL 52, NO 78-11672
- We report for the first time that ZIF-8 crystals undergo an Ostwald-ripening-like process without degradation in the presence of a ligand vapor. The ripening process is dependent on the defect density of the crystals: the more defective the more amenable to the ripening. The process was adapted to synthesize ultra-thin ZIF-8 membranes by vapor-phase secondary growth
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