Defect-induced ripening of zeolitic-imidazolate framework ZIF-8 and its implication to vapor-phase membrane synthesis

Title
Defect-induced ripening of zeolitic-imidazolate framework ZIF-8 and its implication to vapor-phase membrane synthesis
Authors
안희성알버트 이성수권혁택정해권이태희장은희이종석최정규
Issue Date
2016-10
Publisher
Chemical communications
Citation
VOL 52, NO 78-11672
Abstract
We report for the first time that ZIF-8 crystals undergo an Ostwald-ripening-like process without degradation in the presence of a ligand vapor. The ripening process is dependent on the defect density of the crystals: the more defective the more amenable to the ripening. The process was adapted to synthesize ultra-thin ZIF-8 membranes by vapor-phase secondary growth
URI
http://pubs.kist.re.kr/handle/201004/64955
ISSN
1359-7345
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KIST Publication > Article
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