Synthesis of benzo[h]quinoline-based neutral pentacoordinate organosilicon complexes

Title
Synthesis of benzo[h]quinoline-based neutral pentacoordinate organosilicon complexes
Authors
여현욱Yuichiro TokoroKazuo TanakaYoshiki Chujo
Issue Date
2012-09
Publisher
Chemical communications
Citation
VOL 48-8543
Abstract
Reactions of 10-benzo[h]quinolyllithium with a series of organosilanes led to the formation of neutral pentacoordinate complexes. The diethynyl-substituted complex was able to be converted to di(arylethynyl)-substituted ones by the Sonogashira– Hagihara coupling reaction. Electronegative substituents shortened N– Si distances and enhanced fluorescence intensity from the complexes.
URI
http://pubs.kist.re.kr/handle/201004/65936
ISSN
1359-7345
Appears in Collections:
KIST Publication > Article
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