Synthesis of benzo[h]quinoline-based neutral pentacoordinate organosilicon complexes
- Synthesis of benzo[h]quinoline-based neutral pentacoordinate organosilicon complexes
- 여현욱; Yuichiro Tokoro; Kazuo Tanaka; Yoshiki Chujo
- Issue Date
- Chemical communications
- VOL 48-8543
- Reactions of 10-benzo[h]quinolyllithium with a series of organosilanes led to the formation of neutral pentacoordinate complexes. The diethynyl-substituted complex was able to be converted to di(arylethynyl)-substituted ones by the Sonogashira– Hagihara coupling reaction. Electronegative substituents shortened N– Si distances and enhanced fluorescence intensity from the complexes.
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