Synthesis of Zn-MOF incorporating titanium-hydrides as active sites binding H2 molecules

Title
Synthesis of Zn-MOF incorporating titanium-hydrides as active sites binding H2 molecules
Authors
김종식Dong Ok KimDong Wook KimKil Sagong
Keywords
Metal-organic framework; Post-synthetic modification; Site-isolation; Kubasbinding; H2 adsorption
Issue Date
2015-10
Publisher
Journal of solid state chemistry
Citation
VOL 230-117
Abstract
This paper describes the synthetic effort for a Zn-MOF imparting Ti-H as a preferential binding site potentially capturing H-2 molecules via Kubas-type interaction. The formation mechanism of Ti-H innate to the final material was potentially demonstrated to follow a radical dissociation rather than a 3-hydrogen elimination and a C-H reductive elimination.
URI
http://pubs.kist.re.kr/handle/201004/67078
ISSN
0022-4596
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KIST Publication > Article
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