Total Synthesis of (-)-Crinipellin A
- Total Synthesis of (-)-Crinipellin A
- 강택; 송석범; 김원엽; 김병규; 이희윤
- Issue Date
- Journal of the American Chemical Society
- VOL 136, NO 29-10276
- The first total synthesis of (-)-crinipellin A is described. The tetraquinane core skeleton of crinipellin A was assembled through the tandem [2 + 3] cycloaddition reaction of an allenyl diazo substrate containing a cyclopentane ring in a single operation. The absolute stereochemistry was confirmed through the total synthesis.
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