Tandem Cycloaddition Reactions of Allenyl Diazo Compounds Forming Triquinanes via Trimethylenemethane Diyls

Title
Tandem Cycloaddition Reactions of Allenyl Diazo Compounds Forming Triquinanes via Trimethylenemethane Diyls
Authors
강택김원엽윤여권김병규이희윤
Issue Date
2011-11
Publisher
Journal of the American Chemical Society
Citation
VOL 133, NO 45-18053
Abstract
A tandem reaction strategy for forming triquinanes from linear allenyl diazo compounds through an intramolecular 1,3-dipolar cycloaddition reaction of an allenyl diazo group that generates a trimethylenemethane (TMM) diyl followed by an intramolecular [2 + 3] TMM diyl cycloaddition reaction has been developed. The new tandem cycloaddition reaction is readily applicable to the synthesis of complex molecules with high versatility and efficiency.
URI
http://pubs.kist.re.kr/handle/201004/67194
ISSN
0002-7863
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KIST Publication > Article
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