Nickel-Catalyzed Intramolecular C-O Bond Formation: Synthesis of Cyclic Enol Ethers

Title
Nickel-Catalyzed Intramolecular C-O Bond Formation: Synthesis of Cyclic Enol Ethers
Authors
한서정Ryohei DoiBrian M. Stoltz
Issue Date
2016-06
Publisher
Angewandte Chemie international edition
Citation
VOL 55, NO 26-7440
Abstract
An efficient and exceptionally mild intramolecular nickel-catalyzed carbon-oxygen bond-forming reaction between vinyl halides and primary, secondary, and tertiary alcohols has been achieved. Zinc powder was found to be an essential additive for obtaining high catalyst turnover and yields. This operationally simple method allows direct access to cyclic vinyl ethers in high yields in a single step.
URI
http://pubs.kist.re.kr/handle/201004/67403
ISSN
1433-7851
Appears in Collections:
KIST Publication > Article
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