Heterogeneous Transition-Metal-Free Alcohol Oxidation by Graphene Oxide Supported Iodoxybenzoic Acid in Water
- Heterogeneous Transition-Metal-Free Alcohol Oxidation by Graphene Oxide Supported Iodoxybenzoic Acid in Water
- 김영오; Yo-Han Kim; Hyung-Seok Jang; So-Dam Ahn; Sewon Yeo; Sang-Myung Lee; Yoon-Sik Lee
- Issue Date
- VOL 24, NO 17-2286
- The metal-free oxidation of organic compounds is one of the most demanding reactions in chemical industries. As such, iodoxybenzoic acid (IBX) is an attractive reagent due to its metal-free oxidative activity. To apply IBX for the alcohol oxidation in water, IBX was immobilized on graphene oxide (GO). GO-supported IBX reagent exhibited excellent performance for alcohol oxidation reaction in water with greater than 90% selectivity. It could be reused without significant loss of oxidative activity.
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