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dc.contributor.author김형준-
dc.contributor.author장종현-
dc.contributor.author유성종-
dc.contributor.author김진영-
dc.contributor.author최인수-
dc.contributor.authorYoo Eil Jung-
dc.contributor.author이창연-
dc.date.accessioned2021-06-09T04:20:26Z-
dc.date.available2021-06-09T04:20:26Z-
dc.date.issued2017-01-
dc.identifier.citationVOL 8, NO 1-68-
dc.identifier.issn2093-8551-
dc.identifier.other51120-
dc.identifier.urihttp://pubs.kist.re.kr/handle/201004/67893-
dc.description.abstractElectrochemical conversion of CO2 and production of H-2 were attempted on a three-dimensionally ordered, porous metal organic framework (MOF-74) in which transition metals (Co, Ni, and Zn) were impregnated. A lab-scale proton exchange membrane-based electrolyzer was fabricated and used for the reduction of CO2. Real-time gas chromatography enabled the instantaneous measurement of the amount of carbon monoxide and hydrogen produced. Comprehensive calculations, based on electrochemical measurements and gaseous product analysis, presented a time-dependent selectivity of the produced gases. M-MOF-74 samples with different central metals were successfully obtained because of the simple synthetic process. It was revealed that Co- and Ni-MOF-74 selectively produce hydrogen gas, while Zn-MOF-74 successfully generates a mixture of carbon monoxide and hydrogen. The results indicated that M-MOF-74 can be used as an electrocatalyst to selectively convert CO2 into useful chemicals.-
dc.publisherJournal of electrochemical science and technology-
dc.titleFacile Synthesis of M-MOF-74 (M=Co, Ni, Zn) and its Applica- tion as an ElectroCatalyst for Electrochemical CO2 Conversion and H2 Production-
dc.typeArticle-
dc.relation.page6168-
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