Atroposelective Synthesis of PINAP via Dynamic Kinetic Asymmetric Transformation

Title
Atroposelective Synthesis of PINAP via Dynamic Kinetic Asymmetric Transformation
Authors
한서정Vikram BhatBrian M. StoltzScott C. Virgil
Issue Date
2019-02
Publisher
Advanced synthesis & catalysis
Citation
VOL 361, NO 3-444
Abstract
The atroposelective synthesis of PINAP ligands has been accomplished via a palladiumcatalyzed CP coupling process through dynamic kinetic asymmetric transformation. These catalytic conditions allow access to a wide variety of alkoxyand benzyloxy-substituted PINAP ligands in high enantiomeric excess. The methods described in this communication afford valuable P,N ligands in good yields and high enantioselectivity using low catalyst loading
URI
http://pubs.kist.re.kr/handle/201004/69053
ISSN
1615-4150
Appears in Collections:
KIST Publication > Article
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