Optimized preparation of activated carbon from municipal sewage sludge and application to the adsorption of azo dye from aqueous solutions

Title
Optimized preparation of activated carbon from municipal sewage sludge and application to the adsorption of azo dye from aqueous solutions
Authors
정경원이선용이영재
Keywords
Municipal sewage sludge; Activated carbon; Response surface methodology; Box-Behnken design; Azo dye; Adsorption
Issue Date
2019-03
Publisher
Environmental Progress & Sustainable Energy
Citation
VOL 38, NO S1-S276
Abstract
In this study, the conditions for preparation of active carbon from municipal sewage sludge (MSS) were optimized from application to the efficient removal of the azo dye, Acid Orange 7 (AO7), from aqueous solutions. To maximize the adsorption capacity (response variable) of the MSS-derived activated carbon (MSS-AC), a 3k Box– Behnken design based on response surface methodology was used to simultaneously optimize five important conditions (independent variables), that is, carbonizing temperature (400– 600C), carbonizing time (0.5– 2.0 h), impregnation ratio (1.0– 3.5 g KOH/g MSS), activating temperature (600– 800C), and activating time (0.5– 2.0 h). The optimal conditions were established as carbonizing temperature: 509C, carbonizing time: 1.25 h, impregnation ratio: 2.3 g KOH/g MSS, activating temperature: 681C, and activating time: 1.21 h, with an overall desirability function of 0.991. Further, the effects of various key parameters (solution pH, ionic strength, adsorbent dosage, initial concentration, contact time, and temperature) on the adsorption of AO7 on the as-synthesized MSS-AC were elucidated through a series of batch experiments. Adsorption kinetics and isotherm studies revealed that the adsorption process is accurately described by the pseudo-second order and Sips models. The theoretical maximum adsorption capacity of AO7 was found to be ~1410 mg/g at 25C, which is superior to that of the other adsorbents reported to date. Additionally, the intraparticle diffusion model suggested that the adsorption was controlled by both external surface adsorption and intraparticle diffusion. Thermodynamic studies also suggested that the adsorption of AO7 by MASSAC is exothermic and is governed by physisorption.
URI
http://pubs.kist.re.kr/handle/201004/69128
ISSN
1944-7442
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KIST Publication > Article
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