Natural [4+2]-Cyclases

Title
Natural [4+2]-Cyclases
Authors
전병선Shao-An WangMark W. RuszczyckyHung-wen Liu
Issue Date
2017-04
Publisher
Chemical reviews
Citation
VOL 117, NO 8-5388
Abstract
[4 + 2]-Cycloadditions are increasingly being recognized in the biosynthetic pathways of many structurally complex natural products. A relatively small collection of enzymes from these pathways have been demonstrated to increase rates of cyclization and impose stereochemical constraints on the reactions. While mechanistic investigation of these enzymes is just beginning, recent studies have provided new insights with implications for understanding their biosynthetic roles, mechanisms of catalysis, and evolutionary origin.
URI
http://pubs.kist.re.kr/handle/201004/69174
ISSN
0009-2665
Appears in Collections:
KIST Publication > Article
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