RuO2 nanocluster as a 4-in-1 electrocatalyst for hydrogen and oxygen electrochemistry
- RuO2 nanocluster as a 4-in-1 electrocatalyst for hydrogen and oxygen electrochemistry
- 장종현; 박한샘; Juchan Yang; 조민경; Yeongdae Lee; Seonghun Cho; 임성대; Byeong-Su Kim; 송현곤
- Issue Date
- Nano energy
- VOL 55-58
- Partially hydrous RuO2 nanocluster embedded in a carbon matrix (x-RuO2@C with x  =  hydration degree = 0.27 or 0.27@C) is presented as a bifunctional catalyst for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) for water splitting. Symmetric water electrolyzers based on 0.27-RuO2@C for both electrodes showed smaller potential gaps between HER and OER at pH 0, pH 14 and even pH 7 than conventional asymmetric electrolyzers based on two different catalysts (Pt/C; Ir/C) that have been known as the best catalysts for HER and OER respectively. Moreover, 0.27-RuO2@C showed another bifunctional electroactivity for fuel cell electrochemistry involving hydrogen oxidation reaction (HOR) and oxygen reduction reaction (ORR) that are the backward reactions of HER and OER respectively. Pt-level HOR electroactivity was obtained from 0.27-RuO2@C, while its ORR activity was inferior to that of Pt with 200  mV higher overpotential required. The tetra-functionality of 0.27-RuO2@C showed the possibility of realizing single-catalyst regenerative fuel cells.
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