Dehydrogenation of formic acid using molecular Rh and Ir catalysts immobilized on bipyridine-based covalent triazine frameworks

Title
Dehydrogenation of formic acid using molecular Rh and Ir catalysts immobilized on bipyridine-based covalent triazine frameworks
Authors
김홍곤구니야 하리야나담 구나세카윤성호
Keywords
formic acid; dehydrogenation; Rh catalyst; Ir catalyst; triazine framework
Issue Date
2019-04
Publisher
Sustainable Energy & Fuels
Citation
VOL 3, NO 4-1047
Abstract
In this study, catalytic dehydrogenation of formic acid into H2/CO2 using half-sandwich Rh(III)/Ir(III) catalysts immobilized on variable dimensions of bipyridine-based covalent triazine frameworks (bpy-CTFs) has been described for the first time with a highest initial turnover frequency of 7930 h− 1. A systematic study on the influence of the central metal cation (Rh vs. Ir), CTF architectures and amount of metal loadings on the CTF is presented.
URI
http://pubs.kist.re.kr/handle/201004/69760
ISSN
2398-4902
Appears in Collections:
KIST Publication > Article
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