A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F and Perophoramidine

Title
A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F and Perophoramidine
Authors
한서정Florian VogtShyam KrishnanJeremy A. MayMichele GattiScott C. VirgilBrian M. Stoltz
Issue Date
2014-06
Publisher
Organic letters
Citation
VOL 16, NO 12-3319
Abstract
An efficient, unified, and stereodivergent approach toward communesin F and perophoramidine was examined. The C(3) all-carbon quaternary center of an oxindole was smoothly constructed by base-promoted indolone-malonate alkylation chemistry. The complementary relative stereochemistry of the crucial vicinal quaternary centers found in communesin F and perophoramidine was selectively installed by substrate-controlled decarboxylative allylic alkylations.
URI
http://pubs.kist.re.kr/handle/201004/70200
ISSN
1523-7060
Appears in Collections:
KIST Publication > Article
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