A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F and Perophoramidine
- A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F and Perophoramidine
- 한서정; Florian Vogt; Shyam Krishnan; Jeremy A. May; Michele Gatti; Scott C. Virgil; Brian M. Stoltz
- Issue Date
- Organic letters
- VOL 16, NO 12-3319
- An efficient, unified, and stereodivergent approach toward communesin F and perophoramidine was examined. The C(3) all-carbon quaternary center of an oxindole was smoothly constructed by base-promoted indolone-malonate alkylation chemistry. The complementary relative stereochemistry of the crucial vicinal quaternary centers found in communesin F and perophoramidine was selectively installed by substrate-controlled decarboxylative allylic alkylations.
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