Hydrogenation of CO2 to Formate using a Simple, Recyclable, and Efficient Heterogeneous Catalyst

Title
Hydrogenation of CO2 to Formate using a Simple, Recyclable, and Efficient Heterogeneous Catalyst
Authors
정광덕구니야 하리야나담 구나세카윤성호
Keywords
CO2 hydrogenation; COP; formic acid
Issue Date
2019-03
Publisher
Inorganic chemistry
Citation
VOL 58, NO 6-3723
Abstract
1) and selectivity. In addition, the catalyst excellently maintains its efficiency over successive runs and produces a maximum final formate concentration of ∼2.1 M in just 2.5 h with a conversion of 12% in regard to CO2 feed. The apparent advantages of air stability, ease of handling, simplicity, the use of a readily available metal precursor, and the outstanding catalytic performance make [bpy-CTF-RuCl3] one of the possible candidates for realizing the large-scale production of formic acid/formate by CO2 hydrogenation.; Today, one of the most imperative targets to realize the conversions of CO2 in industry is the development of practically viable catalytic systems that demonstrate excellent activity, selectivity, and durability. Herein, a simple heterogeneous Ru(III) catalyst is prepared by immobilizing commercially available RuCl3·xH2O onto a bipyridine-functionalized covalent triazine framework, [bpy-CTF-RuCl3], for the first time. This novel catalyst efficiently hydrogenates CO2 into formate with an unprecedented turnover frequency (38800 h&#8211
URI
http://pubs.kist.re.kr/handle/201004/70312
ISSN
0020-1669
Appears in Collections:
KIST Publication > Article
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE