Enhanced catalytic activity of nanostructured, A-site deficient (La0.7Sr0.3)0.95(Co0.2Fe0.8)O3-δ for SOFC cathodes

Title
Enhanced catalytic activity of nanostructured, A-site deficient (La0.7Sr0.3)0.95(Co0.2Fe0.8)O3-δ for SOFC cathodes
Authors
손지원안 캠 티유Ozden CelikbilekFabio AgneseEleonora CaliChristian LenserNorbert H. MenzlerStephen J. SkinnerElisabeth Djurado
Keywords
SOFC; Cathode; LSCF; Catalytic activity
Issue Date
2019-11
Publisher
Journal of materials chemistry. A, Materials for energy and sustainability
Citation
VOL 7, NO 43-25111
Abstract
Lower operating temperatures (≤650 °C) of solid oxide fuel cells (SOFCs) are sought in order to decrease the system costs and improve material compatibility and durability issues. Here, we report A-site deficient (La0.7Sr0.3)0.95(Co0.2Fe0.8)O3− δ (LSCF) perovskite film as a potential high-performance cathode with microstructural details at the nanometre length scale. This cathode exhibits area specific resistance values of as low as 0.037 and 0.1 Ω cm2 in a symmetrical cell and peak power densities of 1.4 and 1.0 W cm− 2 in a Ni/YSZ anode-supported cell at 650 and 600 °C, respectively. These values are among the highest reported data for LSCF-type cathodes. X-ray diffraction and electron microscopy analyses revealed a closely related two-phase perovskite structure for LSCF and a well-dispersed, nanoscale B-site spinel phase (CoFeOx) decorating the LSCF surfaces. Detailed investigations were carried out to correlate the surface to bulk elemental composition changes on the film, the catalytic activity of the spinel phase and the crystal structures of the constituents with the oxygen reduction reaction (ORR) kinetics. The oxygen transport parameters calculated from the electrochemical impedance spectra indicate an increase by one-to-two-orders of magnitude in the oxygen surface-exchange coefficient in comparison to nominally stoichiometric, state-of-the-art La0.6Sr0.4Co0.2Fe0.8O3− δ. Such substantial improvements in the electrode performance were attributed to the catalytically active B-site spinel phase precipitated as a result of the A-site deficiency and to the very high active surface area of the film.
URI
http://pubs.kist.re.kr/handle/201004/70353
ISSN
2050-7488
Appears in Collections:
KIST Publication > Article
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE