Mother Diamine: A Universal Building Block for Making Chiral Ligands from Daughter Diamines to Binol, Binap and Monophos Analogues

Title
Mother Diamine: A Universal Building Block for Making Chiral Ligands from Daughter Diamines to Binol, Binap and Monophos Analogues
Authors
이안수Soon Mog soAlan J. Lough김현우Jik Chin
Issue Date
2014-08
Publisher
Asian Journal of Organic Chemistry
Citation
VOL 3, NO 10-1107
Abstract
“Mother diamine” (MD) or 1,2-bis(2-hydroxy-phenyl)ethylenediamine can be rapidly transformed to a wide variety of chiral ligands including vicinal diamines and analogs of binol (MDdiol), binap (MDdiphos), and monophos (MDphos). The reactivity and stereoselectivity of the MDphos ligands in Rh-catalyzed hydrogenation are highly sensitive to the N,N’-dialkyl substituents
URI
http://pubs.kist.re.kr/handle/201004/70405
ISSN
2193-5807
Appears in Collections:
KIST Publication > Article
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