Bicyclic Bridgehead Phosphoramidite (Briphos) Ligands with Tunable pi-Acceptor Ability and Catalytic Activity in the Rhodium-Catalyzed Conjugate Additions

Title
Bicyclic Bridgehead Phosphoramidite (Briphos) Ligands with Tunable pi-Acceptor Ability and Catalytic Activity in the Rhodium-Catalyzed Conjugate Additions
Authors
이안수Seihwan AhnKyungjun KangMin-Seob SeoYeonjoon KimWoo Youn KimHyunwoo Kim
Issue Date
2014-10
Publisher
Organic letters
Citation
VOL 16, NO 20-5493
Abstract
A new type of bicyclic bridgehead phosphoramidites (briphos) is reported, where the geometrical constraints significantly enhance the pi-acceptor ability compared with its monocyclic analogs. The briphos is shown to be highly efficient and tunable for Rh(I)-catalyzed conjugate additions of aryl boronic acids to alpha,beta-unsaturated ketones and N-tosyl ketimines.
URI
http://pubs.kist.re.kr/handle/201004/70407
ISSN
1523-7060
Appears in Collections:
KIST Publication > Article
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE