Ligand-Controlled Direct Hydroformylation of Trisubstituted Olefins

Title
Ligand-Controlled Direct Hydroformylation of Trisubstituted Olefins
Authors
이안수Taeil ShinHyungsoo KimSungmin KimMin-Seob SeoJonghoon ChoiHyungjun KimHyunwoo Kim
Issue Date
2019-08
Publisher
Organic letters
Citation
VOL 21, NO 15-5792
Abstract
The direct hydroformylation of trisubstituted olefins has been achieved with a combination of a Rh(I) catalyst and a pi-acceptor phosphorus (briphos) ligand. A sterically bulky briphos ligand with a large cone angle that forms a 1:1 complex with Rh(I) is found to be reactive for the hydroformylation of trisubstituted olefins. The aldehyde products were obtained with high diastereoselectivity (>99:1) and regioselectivity (49%-81%).
URI
http://pubs.kist.re.kr/handle/201004/70417
ISSN
1523-7060
Appears in Collections:
KIST Publication > Article
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE