Exceptional Mechanical Properties of Phase-Separation-Free Mo3Se3--Chain-Reinforced Hydrogel Prepared by Polymer Wrapping Process

Title
Exceptional Mechanical Properties of Phase-Separation-Free Mo3Se3--Chain-Reinforced Hydrogel Prepared by Polymer Wrapping Process
Authors
이경은Si Hyun KimSeungbae OhSudong ChaeJin Woong LeeKyung Hwan ChoiJongwha Chang∥ Liyi ShiJae-Young ChoiJung Heon Lee
Issue Date
2019-08
Publisher
Nano letters
Citation
VOL 19, NO 8-5724
Abstract
As Mo3Se3– chain nanowires have dimensions comparable to those of natural hydrogel chains (molecular-level diameters of ∼0.6 nm and lengths of several micrometers) and excellent mechanical strength and flexibility, they have large potential to reinforce hydrogels and improve their mechanical properties. When a Mo3Se3– -chain-nanowire-gelatin composite hydrogel is prepared simply by mixing Mo3Se3– nanowires with gelatin, phase separation of the Mo3Se3– nanowires from the gelatin matrix occurs in the micronetwork, providing only small improvements in their mechanical properties. In contrast, when the surface of the Mo3Se3– nanowire is wrapped with the gelatin polymer, the chemical compatibility of the Mo3Se3– nanowire with the gelatin matrix is significantly improved, which enables the fabrication of a phase-separation-free Mo3Se3– -reinforced gelatin hydrogel. The composite gelatin hydrogel exhibits significantly improved mechanical properties, including a tensile strength of 27.6 kPa, fracture toughness of 26.9 kJ/m3, and elastic modulus of 54.8 kPa, which are 367%, 868%, and 378% higher than those of the pure gelatin hydrogel, respectively. Furthermore, the amount of Mo3Se3– nanowires added in the composite hydrogel is as low as 0.01 wt %. The improvements in the mechanical properties are significantly larger than those for other reported composite hydrogels reinforced with one-dimensional materials.
URI
http://pubs.kist.re.kr/handle/201004/70609
ISSN
1530-6984
Appears in Collections:
KIST Publication > Article
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